1.
Acta Crystallogr E Crystallogr Commun
; 72(Pt 4): 448-51, 2016 Apr 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-27375861
RESUMO
In the title salt, [Eu(C3H7NO)8][PMo12O40], the asymmetric unit comprises one α-Keggin-type [PMo12O40](3-) polyoxidometalate anion and one distorted dodeca-hedral [Eu(C3H7NO)8](3+) complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexa-gonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C-Hâ¯O hydrogen-bonding inter-actions, leading to the formation of a three-dimensional network structure.